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| Names | |
|---|---|
| Other names
(Chloromethyl)trimethylsilane | |
| Identifiers | |
3D model (JSmol) |
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| ChemSpider | |
| ECHA InfoCard | 100.017.326 |
| EC Number |
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PubChem CID |
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CompTox Dashboard (EPA) |
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| Properties | |
| C4H11ClSi | |
| Molar mass | 122.67 g·mol−1 |
| Appearance | colorless liquid |
| Density | 0.886 g cm−3 |
| Boiling point | 97–98 °C (207–208 °F; 370–371 K) |
| Hazards | |
| GHS labelling:[1] | |
   | |
| Danger | |
| H225, H315, H319, H335, H411 | |
| P210, P233, P240, P241, P242, P243, P261, P264, P271, P273, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P391, P403+P233, P403+P235, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references | |
(Trimethylsilyl)methyl chloride is the organosilicon compound with the formula (CH3)3SiCH2Cl. A colorless, volatile liquid, it is an alkylating agent that is employed in organic synthesis, especially as a precursor to (trimethylsilyl)methyllithium. In the presence of triphenylphosphine, it olefinates benzophenones:[2]
- (CH3)3SiCH2Cl + PPh3 + Ar2C=O → Ar2C=CH2 + OPPh3 + (CH3)3SiCl
See also
- Trimethylsilyl chloride, a silyl chloride
References
- ↑ "Chloromethyltrimethylsilane". pubchem.ncbi.nlm.nih.gov. Retrieved 12 January 2022.
- ↑ Hamann, Lawrence G.; Jones, Todd K. (2001). "(Chloromethyl)trimethylsilane". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rc129. ISBN 0471936235.
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